I believe it is two things.So now I don’t understand why the groove on pistons pad side has to be horisontally upside.
How does that matter?
It is a bit hard to make out from your photos, but if you look at the inside bore of the piston, you will see that it is not circular. The scalloped out part should face up (corresponding with the groove facing up), and is there to reduce the chance of air being trapped inside the piston.
View attachment 38768
So true.But chassis will corode faster than that boot I guess
Had a similar situation with a Fiat 500. Ended up being the hoses that were collapsing on the inside (not visible) because of old age and, as mentionned, trapping return fluid. Replacing all hoses in the system corrected the problem.Next time it locks up, try cracking the bleeder open. Chances are that you'll get a spurt of brake fluid and then it will unlock for a while.
You can try replacing the hoses (they can collapse trapping fluid under pressure in the caliper) and rebuilding the offending rear caliper (a real pain because of the e-brake mechanism).
I'm not going straight to master cylinder replacement because only one of your two rear calipers is affected and the problem goes away when the car sits and rests. An MC problem would affect both rear calipers and generally doesn't clear itself.