Today I began the phosphoric cleaning of the tank. The acid that was readily available at my local builders supply (inexpensively) is a pre-diluted solution (40%). At this dilution you could use it full strength as packaged. However the X's tank is about 13 gals, so it would get a bit expensive to do that. Instead I used 2 gals acid and 3 gals hot water. That means I will have to do one end of the tank, then flip it on one side, then the other side, and finally the other end. Furthermore at this dilution it will have to sit overnight to clean a tank as bad as this one. So about a 4 day process. Not for the impatient I agree, but it is the most effective method and will save this tank. I'm the type that would rather spend the time and a few dollars this way than spend a lot of money for a new tank (which I've read has its own issues).
To do the phosphoric cleaning process:
1) Clean as much unwanted material out as possible with plenty of rinsing, physical agitation (eg. shake the tank around with a piece of chain inside if it is that bad), and a degreaser rinse to eliminate any oily coatings (dramatically slows the acids effectiveness).
2) Plug all openings with whatever it takes. Here is what I had on hand; some plastic/vinyl hose caps/plugs (red arrows), a piece of old rubber inner tube with a hose clamp (blue arrow), and a plumbing temporary plug (yellow arrow). The plumbing plug is nice because you can take it in and out easily.
3) Prop up the tank to whatever position you wish to clean. In the above photo it will clean the bottom third or so. With one plug removed (yellow arrow), add the hot (adding heat energy will help the chemical reaction) water to the tank first, then using a funnel pour the acid in second. Keep the garden hose on hand to rinse any spillage and wear appropriate safety gear.
4) Secure the removed plug and shake the tank around to help mix the solution. Then loosen one of the plugs at the top (yellow arrow one in this case) to allow it to vent. Otherwise it will build pressure as the chemical reactions take place and may blow off one of the plugs.
5) Let it sit, in this case overnight. The length of time required will depend on how bad the tank is, what percent of acid solution you have, and the temperature. Occasionally shake the tank around to agitate and keep the solution mixed.
6) Tighten the loosened plug at the top and turn the tank to a new position to clean another portion of it. Loosen another plug to allow venting again. Repeat this until all areas inside are cleaned. The inside surfaces will get a grey color to them when they are clean. This is the phosphate coating that is left from the phosphoric acid's reaction and provides a great protective coating from future rust, etc. Other acids will not do this and that is the main reason for using phosphoric acid. Plus it is a safer acid to work with than most others.
7) Drain the solution from the tank. Save it because it can be reused several times for all types of cleaning and metal prep. Then rinse the tank using some water mixed with baking soda to neutralize it. Here is where the remaining phosphate coating is great, because without it any rinse with water would immediately start new rust formation on the fresh bare metal. Dry the inside thoroughly and it is ready to be put back in the car.
As you can tell from the description of the process, it should be done with the tank out of the vehicle. It is a bit physical (a tank with liquid inside is a little heavy) and takes time for the acid to work. But the general prep and overall process is not difficult.
I'll try to get a picture of the inside when it is done. But I won't risk getting my medical borescope dirty so I might not be able to show much.